Technical demonstration mode
Successfully complete the following modes in order: "Training", "Time Trial", "Gun Shooting", "Survival". Note: Completing each mode will unlock the next mode in the sequence. Then, technical demonstration mode will be unlocked. Use it to watch the CPU demonstrate its best time with the gun.
New textures
Successfully complete the game two times using the same saved game file, and getting a different ending both times by getting the bandana and stealth camouflage. Then during the next (third) time the game is played, reach Ninja without using the bandana or stealth camouflage. If done correctly, Ninja will be red. There will now be new textures for Snake and Ninja and new bonus music during the ending.
Codec
If you keep calling Mei Ling and choose "DO NOT SAVE", she will tell you to stop calling her on the third try. On the fourth call, she will say nothing and prompt you to save or not. Choose not to save again. On the fifth call, she will stick her tongue out and close the channel without prompting to save.
If you keep calling Nastasha Romanenko, she will eventually tell you about her past, and what happened to her parents, which led to her hate for nuclear weapons and of war.
Every time you finish a boss battle or complete a significant event, some members of your support crew (via codec) will reveal their thoughts on the matter.
Calling people while holding some items will drum up an interesting conversation.
Almost everyone lectures Snake while he has his cigarettes equipped.
Calling Campbell when you acquire any kind of weapon will prompt him to on how to use the weapon. If you haven't already called Nastasha, he will tell you Nastasha's frequency.
Call Campbell four times during the Psycho Mantis battle. On the fourth call, he will tell you the secret to beating Mantis.
During boss fights, different characters will give you tips and information.
Call Campbell and Naomi will give a detailed background on the current FOXhound member.
Shooting the rats near the Comm Towers will prompt different responses from Snake's teammates.
Killing the ravens before the boss fight with Raven will provoke the same kind of responses; Master Miller will also correct Snake who calls them crows. Additionally, Raven will be given an extra line when he meets Snake.
All references to the "crows" will also be changed to "ravens" if Snake calls Miller first.
Call Master Miller while walking on a noisy floor. In the PSX version, he tells Snake to try "fitting his socks over his shoes" after Snake expresses his frustration trying to walk stealthily. The line is changed in the remake, however.
If you wait a while to throw away Ocelot's Time Bomb, Deepthroat will call Snake and warn him about the bomb in his equipment.
In the Japanese version, there are two hidden codec frequencies: 140.07 and 140.66. 140.66 plays classic Metal Gear themes, including Discovery, Zanzibar Breeze, and Theme of Solid Snake.
Alternate costume
Successfully complete the game two times using the same saved game file, and getting a different ending both times by getting the bandana and stealth camouflage. Then during the next (third) time the game is played, Snake will change into a tuxedo in the elevator.
Alternate title screen
Alternate tittle screen
At the title screen, press the D-pad to change the background color.
Konami game surprise
Play the game using a memory card that contains a saved game from any prior Konami title (Castlevania, ISS Soccer, Silent Hill, Suikoden, etc.). Then when Psycho Mantis attempts to read your character's mind, he will mention various game titles
Hal's Lab
In the hallway of Nuclear Storage B2, Otacon seems to have scrawled "Hal's Lab" on the door leading to his laboratory. This may be a reference to Hal Labs, where Kojima's close friend and game designer Masahiro Sakurai formerly worked.
Inside "Hal's Lab", a first generation Playstation console with a Dualshock controller can be seen in the middle part of the lab. For the remake, it is replaced with a Gamecube and a Wavebird controller. Statuettes of Mario and Yoshi can also be seen sitting on the console in the upper-right corner.
Meryl
Near the beginning of the game, when entering the air-vent to meet up with the DARPA chief, look into the vent before the chief's to get a first glimpse at Meryl doing sit-ups. If you leave and re-enter, she'll be doing leg stretches and push-ups. On the fourth time, Meryl will have taken her trousers off and repeat the same exercises in her panties.
Pantless Meryl
Follow Meryl into the Women's bathroom and reach the last stall in under five seconds. Meryl will be caught with her pants down during the next sequence.
Humorous Meryl comments
Look at Meryl with the scope or camera.
Box destinations
Equip a box while in the trucks to travel to the destination on the boxes.
Annoy Cambell
Snipe the rats above where you first encounter Wolf or Snipe the ravens when at your second encounter with Raven.
Defeating Psycho Mantis
Plug the controller into port two and press any button before fighting Psycho Mantis. The word "Hideo" will appear in the corner of a black screen. Use controller two to fight against Mantis to keep him from knowing your moves.
Seeing through Psycho Mantis' eyes
When fighting Psycho Mantis, press Triangle to see through his eyes.
Easier driving scene
To get a better view when shooting at Liquid Snake in the driving scene, hold Triangle while shooting the gun.
Mono TV?
If you call Campbell during the Hind D fight, one piece of advice that he'll give you is to listen for the sound of the rotor blades. If the player does not own a stereo television or have the sound settings on Monural, Campbell, Naomi and Mei Ling will express pity towards Snake for not owning a stereo TV set. However, Campbell reassures Snake that he can still beat the Hind.
Ghosts
Take a picture of the following locations using the camera to view hidden ghosts who are KCEJ development team members.
Name
Location
Fujimura
Elevator in the Comm Tower B complex
Fukushima
Heliport; looking out to sea from cliff
Hirano
Elevator in Comm Tower B; deep in the shaft of top level
Ishiyama
Heliport top of building
Ito
Inside elevator to tank hangar
Jerem Blaustein
Sniper Wolf's corpse
Kaneda
The mirror located in the Women's restroom
Kimura
MG underground base; tip of Metal Gear 's railgun
Kinbara
Dark area of stairs
Kitao
Decoy Octopus (fake DARPA chief) corpse
Kobayashi
Rock in canyon
Kobayashi
Johnny Sasaki holding cell, near DARPA chief
Kojima
Otacon lab; the picture frame to the right
Korekado
Men's restroom
Kozyou
Behind the watertank-like structure in the Canyon
Kutome
Observation room
Makimura
Hidden armory store room; behind the weakened wall
Matsuhana
Hallway of corpses; outside Otacons lab
Mizutani
When fighting Metal Gear
Mori
Lowest point of elevator; Comm Tower B
Mukaide
Reflection in wolfdog cave puddle
Muraoka
Water in cargo dock
Nakamura
In Meryl's blood pool; where she is sniped
Negishi
Sewage waterfall
Nishimura
Next to Baker's corpse
Okajima
Maggots of the real DARPA Chef in cell
Onoda
Where Baker is tied up
Sasaki
Picture frames in the Commander's room
Sato
Comm Tower A; roof destroyed by Hind D missiles
Scott Dolph
Deep down in the dark from the walkway between Comm Towers A and B
Shigeno
Heliport,security caera by staircase
Shikama
Electric floor
Shimizu
Wolf dog cave; first crawling point
Shinkawa
Deep in Sniper Wolf's hallway behind the second pillar
Sonoyama
Torture machine
Takade
Ninja room; glass atedga
Tanaka
Heliport; sleeping soldier
Tougo
End of boiler room; in Blast Furnace with the steam
Toyota
Container in the middle of Raven's warehouse
Uehara
Edge of elevator; where the ravens are
Yamashita
Tip of nuke warhead in nuke storage room
Yoshimura
Dead end of air duct
Yoshioka
Bridge on the third floor of the blast furnace
http://www.cheatcc.com/psx/codes/mgs.html & http://metalgear.wikia.com